Hybrid magnetic CoFe2O4@γ-Fe2O3@CTAB nanocomposites as efficient and reusable adsorbents for Remazol Brilliant Blue R dye

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Autor(es): dc.contributormailto:relex@unb.br-
Autor(es): dc.creatorOliveira, Helena Augusta Lisboa de-
Autor(es): dc.creatorGomide, Guilherme-
Autor(es): dc.creatorVieira, Clauber Alex de Melo-
Autor(es): dc.creatorGuerra, Ana Alice Andrade Meireles-
Autor(es): dc.creatorDepeyrot, Jerome-
Autor(es): dc.creatorCampos, Alex Fabiano Cortez-
Data de aceite: dc.date.accessioned2024-10-23T15:19:42Z-
Data de disponibilização: dc.date.available2024-10-23T15:19:42Z-
Data de envio: dc.date.issued2022-11-07-
Data de envio: dc.date.issued2022-11-07-
Data de envio: dc.date.issued2022-09-01-
Fonte completa do material: dc.identifierhttps://repositorio.unb.br/handle/10482/45147-
Fonte completa do material: dc.identifierhttps://doi.org/10.1080/09593330.2022.2115946-
Fonte completa do material: dc.identifierhttps://orcid.org/0000-0002-3021-921X-
Fonte completa do material: dc.identifierhttps://orcid.org/0000-0002-3564-9008-
Fonte completa do material: dc.identifierhttps://orcid.org/0000-0002-1689-573X-
Fonte completa do material: dc.identifierhttps://orcid.org/0000-0002-7918-8522-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/880270-
Descrição: dc.descriptionThe main goal of the present survey was to elaborate, characterize and evaluate the efficiency of ferrite-based nanoparticles modified with cetyltrimethylammonium bromide (CTAB) as potential magnetic nanoadsorbents to remove Remazol Brilliant Blue R (RBBR) from water. It is proposed an innovative nanomaterial architecture based on highly magnetic and chemically stable core@shell nanoparticles covered by an adsorptive surface layer of CTAB (CoFe2O4@γFe2O3@CTAB). Samples of two different mean sizes (7.5 and 14.6 nm) were synthesized using a hydrothermal coprecipitation followed by surface treatment and functionalization. Batch tests were performed to evaluate the influence of contact time, temperature, pH, shaking rate, presence of interferents and mean size on the performance of the proposed nanomaterials. The kinetics of the adsorption process followed the pseudo-second-order model with an equilibrium time of 20 min. The adsorption capacity was estimated by the Langmuir isotherm model and was found to be 56.3 mg/g (smaller size) and 45.6 mg/g (larger size) at pH = 3 and a shaking rate of 400 rpm. The process was spontaneous, exothermic, and showed increased randomness. Sulphate ions negatively impacted the removal of RBBR. The best performance of the nanoadsorbent based on smaller mean sizes can be correlated to its larger surface area. Regeneration and readsorption tests showed that the nanoadsorbents retain more than 80% of their original removal capacity, therefore they can be effectively recycled and reused.-
Publicador: dc.publisherTaylor & Francis-
Relação: dc.relationhttps://www.tandfonline.com/doi/full/10.1080/09593330.2022.2115946-
Direitos: dc.rightsAcesso Restrito-
Palavras-chave: dc.subjectNanoadsorventes magnéticos-
Palavras-chave: dc.subjectRemoção de corantes-
Palavras-chave: dc.subjectRemediação de águas-
Título: dc.titleHybrid magnetic CoFe2O4@γ-Fe2O3@CTAB nanocomposites as efficient and reusable adsorbents for Remazol Brilliant Blue R dye-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional – UNB

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