Synthesis and expansion of bicyclic enol ether: a probable precursor for the synthesis of macrolide (±)-pyrenophorin

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.creatorCosta, Maísa Borges-
Autor(es): dc.creatorMartins, Marcos P.-
Autor(es): dc.creatorAraújo, Hugo Clemente de-
Autor(es): dc.creatorResck, Inês Sabioni-
Data de aceite: dc.date.accessioned2021-10-14T18:29:51Z-
Data de disponibilização: dc.date.available2021-10-14T18:29:51Z-
Data de envio: dc.date.issued2019-01-02-
Data de envio: dc.date.issued2019-01-02-
Data de envio: dc.date.issued2018-
Fonte completa do material: dc.identifierhttp://repositorio.unb.br/handle/10482/33450-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.21577/0103-5053.20170114-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/633111-
Descrição: dc.descriptionA convenient procedure for the synthesis and expansion of bicyclic rings has been developed for the production of probable precursors of non-racemic pyrenophorin, an antibiotic dilactone. The major highlight for this new synthetic methodology came from the use of a readily available reagent of easy manipulation, 9-oxabicyclo[3.3.1]nonane-2,6-diol, for the preparation of the bicyclic intermediate, which sequentially was subjected to oxidative cleavage with butyl nitrite resulted in an isomeric mixture, a dioximedilactone and diisoxazoledilactone.-
Formato: dc.formatapplication/pdf-
Idioma: dc.languageen-
Publicador: dc.publisherSociedade Brasileira de Química-
Direitos: dc.rightsAcesso Aberto-
Direitos: dc.rights(CC BY) - This is an open-access article distributed under the terms of the Creative Commons Attribution License.-
Palavras-chave: dc.subjectQuímica orgânica-
Palavras-chave: dc.subjectAntibióticos-
Título: dc.titleSynthesis and expansion of bicyclic enol ether: a probable precursor for the synthesis of macrolide (±)-pyrenophorin-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional – UNB

Não existem arquivos associados a este item.