Cellulose oxidation and the use of carboxyl cellulose metal complexes in heterogeneous catalytic systems to promote Suzuki-Miyaura coupling and C-O bond formation reaction

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MetadadosDescriçãoIdioma
Autor(es): dc.creatorMartins, Guilherme B. C.-
Autor(es): dc.creatorSantos, Marcelo R. dos-
Autor(es): dc.creatorRodrigues, Marcus V. R.-
Autor(es): dc.creatorSucupira, Renata Rodrigues-
Autor(es): dc.creatorMeneghetti, Luisa-
Autor(es): dc.creatorMonteiro, Adriano L.-
Autor(es): dc.creatorSuarez, Paulo Anselmo Ziani-
Data de aceite: dc.date.accessioned2021-10-14T17:26:50Z-
Data de disponibilização: dc.date.available2021-10-14T17:26:50Z-
Data de envio: dc.date.issued2018-01-04-
Data de envio: dc.date.issued2018-01-04-
Data de envio: dc.date.issued2017-11-
Fonte completa do material: dc.identifierhttp://repositorio.unb.br/handle/10482/30695-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.21577/0103-5053.20170051-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/608091-
Descrição: dc.descriptionThis work shows the modification of microcrystalline cellulose by the selective oxidation of primary hydroxyl groups to carboxylate groups by a 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated system and its application as a heterogeneous ligand by ionic exchange with catalytic metals ions such as palladium, nickel and copper. Afterwards is described the application of the synthesized material as catalyst in coupling reactions such as Suzuki-Miyaura coupling and C−O bond formation reaction in different conditions, which are of great importance for the synthesis of drugs, natural products and new materials such as dendrimers, liquid crystals and polymers with magnetic and optical properties. The carboxyl cellulose matrix shows to have superior catalytic results as a ligand for all coupling reactions. Can be also highlighted the affinity of the carboxyl cellulose ligand in polar solvents such as water and alcohols and its application in mild conditions.-
Formato: dc.formatapplication/pdf-
Idioma: dc.languageen-
Publicador: dc.publisherSociedade Brasileira de Química-
Direitos: dc.rightsAcesso Aberto-
Direitos: dc.rightsJournal of the Brazilian Chemical Society - This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0). Fonte: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017001102064&lng=en&nrm=iso. Acesso em: 1 fev. 2018.-
Palavras-chave: dc.subjectOxidação-
Palavras-chave: dc.subjectLigas (Metalurgia)-
Palavras-chave: dc.subjectReações químicas-
Título: dc.titleCellulose oxidation and the use of carboxyl cellulose metal complexes in heterogeneous catalytic systems to promote Suzuki-Miyaura coupling and C-O bond formation reaction-
Tipo de arquivo: dc.typelivro digital-
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