Facile synthesis of symmetrical 3,3-diarylacrylates by a Heck-Matsuda reaction: an expedient route to biologically active indanones.

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.creatorTaylor, Jason Guy-
Autor(es): dc.creatorRibeiro, Rodrigo da Silva-
Autor(es): dc.creatorCorreia, Carlos Roque Duarte-
Data de aceite: dc.date.accessioned2019-11-06T13:33:31Z-
Data de disponibilização: dc.date.available2019-11-06T13:33:31Z-
Data de envio: dc.date.issued2015-04-09-
Data de envio: dc.date.issued2015-04-09-
Data de envio: dc.date.issued2011-
Fonte completa do material: dc.identifierhttp://www.repositorio.ufop.br/handle/123456789/4979-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/558051-
Descrição: dc.descriptionA simple and straightforward synthesis of symmetrical 3,3-diarylacrylates based on a Heck-Matsuda reaction of arenediazonium salts bearing electron-donating groups with methylacrylates is described. The reaction employs Pd(OAc)2 as catalyst and goes to completion within 1 h affording the corresponding unsaturated diaryl esters in good to high yields. This method permitted the expeditious and efficient synthesis of the anticancer 3-arylindanone 5 in two operative steps in 43% overall yield.-
Idioma: dc.languageen-
Direitos: dc.rightsO Periódico Tetrahedron Letters concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3581340458166.-
Palavras-chave: dc.subjectArenediazonium tetrafluoroborates-
Palavras-chave: dc.subjectHeck-Matsuda-
Palavras-chave: dc.subjectArylation-
Palavras-chave: dc.subjectIndanones-
Palavras-chave: dc.subjectPalladium-
Título: dc.titleFacile synthesis of symmetrical 3,3-diarylacrylates by a Heck-Matsuda reaction: an expedient route to biologically active indanones.-
Aparece nas coleções:Repositório Institucional - UFOP

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