Insight into magnetite nanoparticle phase evolution in solvothermal synthesis through a simple method based on iron chloride and metallic iron.

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.creatorSilva, F. B. F.-
Autor(es): dc.creatorParis, Elaine Cristina-
Autor(es): dc.creatorCosta, Geraldo Magela da-
Autor(es): dc.creatorRibeiro, C.-
Data de aceite: dc.date.accessioned2019-11-06T13:33:20Z-
Data de disponibilização: dc.date.available2019-11-06T13:33:20Z-
Data de envio: dc.date.issued2015-04-14-
Data de envio: dc.date.issued2015-04-14-
Data de envio: dc.date.issued2014-
Fonte completa do material: dc.identifierhttp://www.repositorio.ufop.br/handle/123456789/5088-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/557978-
Descrição: dc.descriptionThis paper presents the development and optimization of the synthesis of magnetic nanoparticles composed of iron oxides by a solvothermal method with benzyl alcohol using iron(III) chloride hexahydrate as a metallic precursor in the substitution of iron(III) acetylacetonate. The synthesis parameters were studied and varied to obtain a high yield of magnetite. Metallic iron was evaluated as a reducing agent and iron source. Furthermore, the use of urea as a precipitation agent was crucial to increasing the yield of magnetite, at once reducing the acidity of the medium and inducing the precipitation of Fe2+ ions. Longer treatment times and no stirring led to an increase in the yield of magnetite, whose formation process followed the Ostwald step rule. The particles were characterized by X-ray diffraction, M¨ossbauer spectroscopy, FTIR, TEM, SEM-FEG and VSM (Vibrating Sample Magnetometry). The phases were quantified by the Rietveld method and M¨ossbauer spectroscopy, and a 97% maximum yield of magnetite was achieved. The polymerization of benzyl alcohol during the solvothermal treatment was shown to play an important role in the nanoparticle capping. The polymerized resin was characterized by FTIR and NMR-1H, and a mechanism for the polymerization reaction was proposed to elucidate the synthetic route and its relationship to particle formation and stability.-
Idioma: dc.languageen-
Direitos: dc.rightsO Periódico RSC Advances concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3581980991838.-
Título: dc.titleInsight into magnetite nanoparticle phase evolution in solvothermal synthesis through a simple method based on iron chloride and metallic iron.-
Aparece nas coleções:Repositório Institucional - UFOP

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