Synthesis, structural and spectroscopic characterization of novel zinc(II) complexes with N-methylsulfonyldithiocarbimato and N-methylsulfonyltrithiocarbimato ligands.

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.creatorOliveira, Marcelo Ribeiro Leite-
Autor(es): dc.creatorPerpétuo, Genivaldo Julio-
Autor(es): dc.creatorJanczak, Jan-
Autor(es): dc.creatorRubinger, Mayura Marques Magalhães-
Data de aceite: dc.date.accessioned2019-11-06T13:32:14Z-
Data de disponibilização: dc.date.available2019-11-06T13:32:14Z-
Data de envio: dc.date.issued2015-02-23-
Data de envio: dc.date.issued2015-02-23-
Data de envio: dc.date.issued2007-
Fonte completa do material: dc.identifierhttp://www.repositorio.ufop.br/handle/123456789/4464-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/557512-
Descrição: dc.descriptionTwo new zinc(II)-complexes, dithiocarbimato (Ph4P)2[Zn(CH3SO2N@CS2)2] (1) and trithiocarbimato (Ph4P)2[Zn(CH3SO2N@CS3)2] (2), were obtained in the crystalline form by the reaction of potassium N-methylsulfonyldithiocarbimate (RSO2N@CS2K2) with zinc(II) acetate dihydrate and tetraphenylphosphonium chloride in dimethylformamide. Both complexes crystallize in the monoclinic system. The central Zn(II) ion has a distorted tetrahedral coordination in both compounds. In 1 the dithiocarbimato ligand coordinates via two S atoms while in 2 the trithiocarbimato ligand coordinates via S and N atoms. Both complexes were also characterized by IR, 1H NMR and 13C NMR spectroscopies. Compound 2 is the first example of a zinc(II)-trithiocarbimato complex.-
Idioma: dc.languageen-
Direitos: dc.rightsO Periódico Polyhedron concede permissão para depósito do artigo no Repositório Institucional da UFOP. Número da licença: 3564801473075.-
Palavras-chave: dc.subjectDithiocarbimate-
Palavras-chave: dc.subjectTrithiocarbimate-
Palavras-chave: dc.subjectZinc complexes-
Palavras-chave: dc.subjectCrystal structure-
Título: dc.titleSynthesis, structural and spectroscopic characterization of novel zinc(II) complexes with N-methylsulfonyldithiocarbimato and N-methylsulfonyltrithiocarbimato ligands.-
Aparece nas coleções:Repositório Institucional - UFOP

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