The reverse fluorine Perlin-like effect and related stereoelectronic interactions

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.creatorSilla, Josué M.-
Autor(es): dc.creatorFreitas, Matheus P.-
Autor(es): dc.creatorCormanich, Rodrigo A.-
Autor(es): dc.creatorRittner, Roberto-
Data de aceite: dc.date.accessioned2026-02-09T11:24:54Z-
Data de disponibilização: dc.date.available2026-02-09T11:24:54Z-
Data de envio: dc.date.issued2020-07-12-
Data de envio: dc.date.issued2020-07-12-
Data de envio: dc.date.issued2014-06-06-
Fonte completa do material: dc.identifierhttps://repositorio.ufla.br/handle/1/41845-
Fonte completa do material: dc.identifierhttps://pubs.acs.org/doi/10.1021/jo501025a-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/1140322-
Descrição: dc.descriptionA similar effect to the well-known reverse Perlin effect was observed on the 1JC–F coupling constants of α- and β-d-glucopyranosyl fluoride tetracetate, both in nonpolar and polar solution. This can be called “reverse fluorine Perlin-like effect”, and it is shown to be ruled by dipolar interactions rather than by hyperconjugation. The reverse fluorine Perlin-like effect does not have a general relationship with the anomeric effect, and it can be useful to determine the structure and stereochemistry of organofluorine compounds.-
Idioma: dc.languageen-
Publicador: dc.publisherAmerican Chemical Society (ACS)-
Direitos: dc.rightsrestrictAccess-
???dc.source???: dc.sourceJournal of Organic Chemistry (JOC)-
Palavras-chave: dc.subjectElectrostatics-
Palavras-chave: dc.subjectFluorine-
Palavras-chave: dc.subjectMolecular properties-
Palavras-chave: dc.subjectMolecular structure-
Palavras-chave: dc.subjectGases-
Título: dc.titleThe reverse fluorine Perlin-like effect and related stereoelectronic interactions-
Tipo de arquivo: dc.typeArtigo-
Aparece nas coleções:Repositório Institucional da Universidade Federal de Lavras (RIUFLA)

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