Biochar-based catalyst derived from corn husk waste for efficient hydrogen generation via NaBH4 hydrolysis.

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MetadadosDescriçãoIdioma
Autor(es): dc.creatorRuiz Lopez, Melany Alejandra-
Autor(es): dc.creatorFajardo, Humberto Vieira-
Autor(es): dc.creatorFerreira, Guilherme Max Dias-
Autor(es): dc.creatorSouza, Thamiris Ferreira de-
Autor(es): dc.creatorPark, Vinícius Novaes-
Autor(es): dc.creatorSantos, Aysha Fernanda Soares Menezes dos-
Autor(es): dc.creatorRodrigues, Thenner Silva-
Autor(es): dc.creatorRamos, Luka Duarte-
Autor(es): dc.creatorFerreira, Gabriel Max Dias-
Data de aceite: dc.date.accessioned2025-08-21T15:58:27Z-
Data de disponibilização: dc.date.available2025-08-21T15:58:27Z-
Data de envio: dc.date.issued2025-03-20-
Data de envio: dc.date.issued2023-
Fonte completa do material: dc.identifierhttps://www.repositorio.ufop.br/handle/123456789/19982-
Fonte completa do material: dc.identifierhttps://link.springer.com/article/10.1007/s12649-024-02756-1-
Fonte completa do material: dc.identifierhttps://doi.org/10.1007/s12649-024-02756-1-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/1028980-
Descrição: dc.descriptionBiochars from agricultural waste are sustainable and eco-friendly alternatives in catalyst development for hydrogen evolu- tion. However, the use of these materials in hydrogen generation remains underexplored, and some fundamental aspects have not yet been addressed. Here, we synthesized cobalt-impregnated biochars derived from corn husk modified with CoCl2 and employed them as catalysts in NaBH4 hydrolysis. Characterization was made by FTIR, XRD, TGA, MEV, TEM and EDS. The incorporation of cobalt into biochar increased its thermal stability, made its surface rougher and more heterogeneous, and increased its crystallinity by the presence of CoCl2 and Co3O4. The catalytic activity of the material depended on the content of impregnated cobalt and the NaOH and NaBH4 concentrations in the medium. Biochar with a higher cobalt content exhibited superior catalytic activity (hydrogen generation rate (HGR)=271.4 mL/(min·g) and Ea = 54.75 KJ/mol) under the best conditions at 25 °C (10% w/v NaOH, 5% w/v NaBH4, and 0.05 g of biochar). The catalyst experienced deactivation after two usage cycles, attributed to the formation of Co(OH)2 from CoCl2 and Co3O4 on the biochar surface under highly basic conditions during the reaction, as well as the formation of borate. Despite this, the biochar structure remained intact after the reaction, demonstrating the robustness of this carbonaceous material as a support. These findings are essential for guiding future research on metallic catalysts supported on biochar derived from biomass pretreated with metal salts for hydrogen generation via NaBH4 hydrolysis.-
Formato: dc.formatapplication/pdf-
Idioma: dc.languageen-
Direitos: dc.rightsrestrito-
Palavras-chave: dc.subjectCorn husk-
Palavras-chave: dc.subjectHydrogen production-
Palavras-chave: dc.subjectPyrolysis-
Palavras-chave: dc.subjectCobalt-
Palavras-chave: dc.subjectHeterogeneous catalyst-
Título: dc.titleBiochar-based catalyst derived from corn husk waste for efficient hydrogen generation via NaBH4 hydrolysis.-
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