Synthesis and molecular structure of a chiral bipyridine-menthol ether.

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.creatorCarvalho, Alexandre Bizzotto de-
Autor(es): dc.creatorDiogo, Gabriela Maciel-
Autor(es): dc.creatorCorrea, Rodrigo de Souza-
Autor(es): dc.creatorTaylor, Jason Guy-
Data de aceite: dc.date.accessioned2025-08-21T15:51:41Z-
Data de disponibilização: dc.date.available2025-08-21T15:51:41Z-
Data de envio: dc.date.issued2022-01-09-
Data de envio: dc.date.issued2022-01-09-
Data de envio: dc.date.issued2019-
Fonte completa do material: dc.identifierhttp://www.repositorio.ufop.br/jspui/handle/123456789/14303-
Fonte completa do material: dc.identifierhttps://link.springer.com/article/10.1134/S0022476620050121-
Fonte completa do material: dc.identifierhttps://doi.org/10.1134/S0022476620050121-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/1026004-
Descrição: dc.descriptionThis paper presents the synthesis and structural characterization of 6,6′-bis[(1R,2S,5R)-isomenthoxy]-2,2′- bipyridine obtained by homocoupling of chiral pyridyl-ether 2-bromo-6-[(1R,2S,5R)-isomenthoxy]- pyridine. The two-step synthetic procedure afforded chiral bipyridine in a good yield and the structure of the compound is determined by X-ray diffraction. It crystallizes in a non-centrosymmetric chiral crystal structure type (P21, a = 10.7543(8) Å, b = 8.4488(6) Å, c = 15.8964(10) Å, β = 104.035(7)°, V = 1401.24(17) Å3 , Z = 2). Moreover, the compound is characterized by FTIR, high resolution mass spectrometry and its complexation capacity to transition metals is studied by UV-Vis spectroscopy.-
Formato: dc.formatapplication/pdf-
Idioma: dc.languageen-
Direitos: dc.rightsrestrito-
Palavras-chave: dc.subjectMenthol-
Palavras-chave: dc.subjectLigand-
Palavras-chave: dc.subjectMetal-
Palavras-chave: dc.subjectCrystal structure-
Título: dc.titleSynthesis and molecular structure of a chiral bipyridine-menthol ether.-
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