cis and trans isomers of Ru(III)-based complexes with lapachol : x-ray diffractions and DFT theoretical insights.

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.creatorAlves, André Vicente-
Autor(es): dc.creatorSilveira, Rafael G.-
Autor(es): dc.creatorBarbosa, Marília Imaculada Frazão-
Autor(es): dc.creatorEllena, Javier Alcides-
Autor(es): dc.creatorBatista, Alzir Azevedo-
Autor(es): dc.creatorCorrea, Rodrigo de Souza-
Data de aceite: dc.date.accessioned2025-08-21T15:46:47Z-
Data de disponibilização: dc.date.available2025-08-21T15:46:47Z-
Data de envio: dc.date.issued2025-02-25-
Data de envio: dc.date.issued2023-
Fonte completa do material: dc.identifierhttps://www.repositorio.ufop.br/handle/123456789/19792-
Fonte completa do material: dc.identifierhttps://www.tandfonline.com/doi/pdf/10.1080/15421406.2024.2323789-
Fonte completa do material: dc.identifierhttps://doi.org/10.1080/15421406.2024.2323789-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/1023895-
Descrição: dc.descriptionLapachol (lap) is widely studied due to its biological application, as well as its importance in the coordination chemistry field. The struc- ture of cis and trans isomers of new ruthenium(III) complex [RuCl2(PPh3)2(lap)] is reported here. The complexes present one mol- ecule of the natural product lapachol, coordinated as bidentate by oxygen atoms, two monodentate triphenylphosphines and two chlorido ligands in a cis or trans configurations. All neutral complexes were characterized by single-crystal X-ray diffraction and these data were compared with Density Functional Theory (DFT) data results. This study highlights the stereochemistry and structural versatility of metal complexes containing lapachol as ligand.-
Formato: dc.formatapplication/pdf-
Idioma: dc.languageen-
Direitos: dc.rightsrestrito-
Palavras-chave: dc.subjectCis and trans isomers-
Palavras-chave: dc.subjectLapachol-
Palavras-chave: dc.subjectTuthenium-
Palavras-chave: dc.subjectComplexes-
Título: dc.titlecis and trans isomers of Ru(III)-based complexes with lapachol : x-ray diffractions and DFT theoretical insights.-
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