Structural and spectroscopic characterization of bis[1- (diaminomethylene)thiouron-1-ium] naphthalene-1,5-disulfonate.

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.creatorFelix, Marcela Campanha-
Autor(es): dc.creatorPerpétuo, Genivaldo Julio-
Autor(es): dc.creatorJanczak, Jan-
Data de aceite: dc.date.accessioned2025-08-21T15:26:21Z-
Data de disponibilização: dc.date.available2025-08-21T15:26:21Z-
Data de envio: dc.date.issued2019-06-07-
Data de envio: dc.date.issued2019-06-07-
Data de envio: dc.date.issued2018-
Fonte completa do material: dc.identifierhttp://www.repositorio.ufop.br/handle/123456789/11475-
Fonte completa do material: dc.identifierhttps://www.sciencedirect.com/science/article/pii/S0022286018307348-
Fonte completa do material: dc.identifierhttps://doi.org/10.1016/j.molstruc.2018.06.033-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/capes/1014745-
Descrição: dc.descriptionSingle crystals of bis[1-(diaminomethylene)thiouron-1-ium] naphthalene-1,5-disulfonate (1) are grown using growth solution technique. The compound crystallizes in the centrosymmetric C2/c space group of the monoclinic system with four molecules per unit cell. The arrangement of oppositely charged units, i.e. 1-(diaminomethylene)thiouron-1-ium cations and naphthalene-1,5-disulfonate anions in the crystal is mainly determined by the ionic and the NeH/O hydrogen bonding interactions. Hirshfeld surface and the analysis of 2D fingerprint plots are illustrating both qualitatively and quantitatively interactions governing the supramolecular arrangement. The compound was also characterized by FT-IR and Raman spectroscopies. The vibrational assignment of the characteristic bands of the functional groups have been supported by the isotopic frequency shift.-
Formato: dc.formatapplication/pdf-
Idioma: dc.languageen-
Direitos: dc.rightsrestrito-
Palavras-chave: dc.subjectCrystal structure-
Palavras-chave: dc.subjectHydrogen bond-
Palavras-chave: dc.subjectHirshfeld surface-
Palavras-chave: dc.subjectVibrational spectroscopy-
Título: dc.titleStructural and spectroscopic characterization of bis[1- (diaminomethylene)thiouron-1-ium] naphthalene-1,5-disulfonate.-
Aparece nas coleções:Repositório Institucional - UFOP

Não existem arquivos associados a este item.