Percolation Threshold of Bacterial Nanocrystals in Biopolymeric Matrices to Build Up Strengthened Biobased Food Packaging

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Autor(es): dc.contributorUniversidade Estadual Paulista (UNESP)-
Autor(es): dc.contributorBrazilian Center for Research in Energy and Materials (CNPEM)-
Autor(es): dc.creatorda Costa, Fabíola Medeiros-
Autor(es): dc.creatorMelo, Pamela Thais Sousa-
Autor(es): dc.creatorNishimoto, Pedro Henrique Kenzo-
Autor(es): dc.creatorLorevice, Marcos Vinicius-
Autor(es): dc.creatorAouada, Fauze Ahmad-
Autor(es): dc.creatorde Moura, Márcia Regina-
Data de aceite: dc.date.accessioned2025-08-21T20:37:28Z-
Data de disponibilização: dc.date.available2025-08-21T20:37:28Z-
Data de envio: dc.date.issued2025-04-29-
Data de envio: dc.date.issued2025-04-01-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.3390/foods14071123-
Fonte completa do material: dc.identifierhttps://hdl.handle.net/11449/304447-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/304447-
Descrição: dc.descriptionBacterial cellulose nanocrystals (BCNCs) extracted from cellulose residues, resulting from film-cutting operations used for the commercial production of dressings, were studied as reinforcement for films based on gelatin, pectin, and hydroxypropylmethyl cellulose (HPMC). The biopolymer matrices differ in their monomer and functional group (gelatin: -COOH and -NH; pectin: -COOH and HPMC -OH). The addition of BCNCs into a polymer matrix for biopolymeric nanocomposite formulation was based on values around the theoretical percolation threshold. The results of this study showed that the BCNCs had a diameter and mean length range of (27 ± 1) nm and (180 ± 10) nm, respectively, producing films reaching 120.13 MPa of tensile strength, 10.9 GPa of Young’s modulus, and a toughness of 335.17 × 106 J/m3. All films showed good transparency and a smooth surface. Surface micrographs (SEM) revealed homogeneous, compact, smooth regions, and no macropores. The crystallinity index of the BCNCs produced was 68.69%. The crystallinity of the gelatin, pectin, and HPMC films improved from 10.25 to 44.61%, from 29.79 to 53.04%, and from 18.81 to 39.88%, respectively. These results show the possibility of using films for freeze-dried food packaging.-
Descrição: dc.descriptionHybrid Composites and Nanocomposites Group (GCNH) Department of Physics and Chemistry School of Engineering São Paulo State University (UNESP), Ilha Solteira, SP-
Descrição: dc.descriptionBrazilian Nanotechnology National Laboratory (LNNano) Brazilian Center for Research in Energy and Materials (CNPEM), SP-
Descrição: dc.descriptionHybrid Composites and Nanocomposites Group (GCNH) Department of Physics and Chemistry School of Engineering São Paulo State University (UNESP), Ilha Solteira, SP-
Idioma: dc.languageen-
Relação: dc.relationFoods-
???dc.source???: dc.sourceScopus-
Palavras-chave: dc.subjectbacterial cellulose nanocrystals-
Palavras-chave: dc.subjectgelatin-
Palavras-chave: dc.subjectHPMC-
Palavras-chave: dc.subjectpackaging-
Palavras-chave: dc.subjectpectin-
Palavras-chave: dc.subjectpercolation threshold-
Título: dc.titlePercolation Threshold of Bacterial Nanocrystals in Biopolymeric Matrices to Build Up Strengthened Biobased Food Packaging-
Tipo de arquivo: dc.typelivro digital-
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