Conversion of 1-butanol into High Value-Added Chemicals by Mixed Metal Oxides: The Influence of Co2+, Ni2+, and Zn2+ into Condensed Phase Products Distribution

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Autor(es): dc.contributorUniversidade Estadual Paulista (UNESP)-
Autor(es): dc.contributorFacultad de Ciencias Básicas-
Autor(es): dc.contributorFederal University of Sao Joao Del Rei-
Autor(es): dc.creatorVargas, Jorge Andrés Mora-
Autor(es): dc.creatorde Paula Dias, Rafael Mafra-
Autor(es): dc.creatorde Lima, Livia Padilha-
Autor(es): dc.creatorOrtega, Julieth Orduña-
Autor(es): dc.creatorBoscolo, Mauricio-
Autor(es): dc.creatorMetzker, Gustavo-
Data de aceite: dc.date.accessioned2025-08-21T21:46:19Z-
Data de disponibilização: dc.date.available2025-08-21T21:46:19Z-
Data de envio: dc.date.issued2025-04-29-
Data de envio: dc.date.issued2024-05-01-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.1007/s10562-023-04476-y-
Fonte completa do material: dc.identifierhttps://hdl.handle.net/11449/301311-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/301311-
Descrição: dc.descriptionAbstract: The catalytic transformation of 1-butanol into condensed products by mixed metal oxides, based on Mg2+ and Al3+, containing Co2+, Ni2+, and Zn2+, into ethers, aldehydes, alkenes, ketones, alkylbenzenes, and phenolic compounds is described. The reactions were conducted at 550 and 600 °C, with and without methanol co-feeding. The presence of Co2+, Ni2+, and Zn2+ in the catalyst structure, together with the reaction temperature and methanol co-feeding, allowed the modulation of the yield and selectivity of each class of product. Also, to the best of our knowledge, this is the first time that phenolic compounds were produced from 1-butanol, and due to the nature of the condensed products found, the Robinson annulation was proposed as the reaction mechanism. The methodology herein described uses a renewable carbon source, is greener than the current ones for synthesizing the classes of compounds mentioned earlier, and can be an alternative for raw materials currently obtained exclusively from petroleum. Graphical Abstract: (Figure presented.)-
Descrição: dc.descriptionUniversidad Santiago de Cali-
Descrição: dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)-
Descrição: dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)-
Descrição: dc.descriptionDepartment of Chemistry and Environmental Sciences Sao Paulo State University (UNESP-IBILCE), SP-
Descrição: dc.descriptionUniversidad Santiago de Cali (USC) Facultad de Ciencias Básicas, Campus Pampalinda-
Descrição: dc.descriptionDepartment of Chemistry Biotechnology and Bioprocesses Engineering Federal University of Sao Joao Del Rei, MG-
Descrição: dc.descriptionDepartment of Chemistry and Environmental Sciences Sao Paulo State University (UNESP-IBILCE), SP-
Descrição: dc.descriptionUniversidad Santiago de Cali: 06-2023-
Descrição: dc.descriptionCAPES: 1760327-
Descrição: dc.descriptionFAPESP: 2013/23886-4-
Descrição: dc.descriptionFAPESP: 2017/09520-8-
Descrição: dc.descriptionFAPESP: 2017/13230-5-
Descrição: dc.descriptionFAPESP: 2020/02471-4-
Descrição: dc.descriptionUniversidad Santiago de Cali: 939-621121-2827-
Formato: dc.format2305-2313-
Idioma: dc.languageen-
Relação: dc.relationCatalysis Letters-
???dc.source???: dc.sourceScopus-
Palavras-chave: dc.subject1-butanol-
Palavras-chave: dc.subjectGreen chemistry-
Palavras-chave: dc.subjectMixed metal oxide-
Palavras-chave: dc.subjectRaw chemicals-
Título: dc.titleConversion of 1-butanol into High Value-Added Chemicals by Mixed Metal Oxides: The Influence of Co2+, Ni2+, and Zn2+ into Condensed Phase Products Distribution-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional - Unesp

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