Elevated concentrations of halogenated flame retardants in waste childcare articles from Ireland

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Autor(es): dc.contributorUniversity of Birmingham-
Autor(es): dc.contributorThe University of Queensland-
Autor(es): dc.contributorNational University of Ireland-
Autor(es): dc.contributorUniversidade Estadual Paulista (UNESP)-
Autor(es): dc.creatorHarrad, Stuart-
Autor(es): dc.creatorDrage, Daniel-
Autor(es): dc.creatorSharkey, Martin-
Autor(es): dc.creatorStubbings, Will-
Autor(es): dc.creatorAlghamdi, Misbah-
Autor(es): dc.creatorBerresheim, Harald-
Autor(es): dc.creatorCoggins, Marie-
Autor(es): dc.creatorRosa, André Henrique-
Data de aceite: dc.date.accessioned2025-08-21T20:14:07Z-
Data de disponibilização: dc.date.available2025-08-21T20:14:07Z-
Data de envio: dc.date.issued2023-07-29-
Data de envio: dc.date.issued2023-07-29-
Data de envio: dc.date.issued2023-01-14-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.1016/j.envpol.2022.120732-
Fonte completa do material: dc.identifierhttp://hdl.handle.net/11449/246424-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/246424-
Descrição: dc.descriptionConcentrations of legacy and alternative halogenated flame retardants (HFRs) including chlorinated organophosphate esters (Cl-OPEs), were measured in waste childcare articles (n = 275 for Cl-OPEs, n = 187 for other HFRs) from the Republic of Ireland between 2019 and 2020. Articles studied comprised foams and fabrics from: child car seats, cot mattresses, changing mats, pushchairs, prams, and related items. Fifteen articles (7.7%) exceeded the European Union limit value of 1000 mg/kg for polybrominated diphenyl ethers (PBDEs) (all due to BDE-209), an additional 15 exceeded the limit for hexabromocyclododecane (HBCDD), with 7 articles exceeding the limit for both PBDEs and HBCDD. An even greater proportion of articles contained concentrations exceeding 1000 mg/kg for: tris(1-chloro-2-propyl) phosphate (TCIPP) (n = 73, 27%) and tris(1,3-dichloro-2-propyl) phosphate (TDCIPP) (n = 58, 21%), with concentrations greater than 1000 mg/kg also observed for: tris(2-chloroethyl) phosphate (TCEP) (n = 14, 5.1% articles), 2-ethylhexyl tetrabromobenzoate (EH-TBB) (n = 7, 3.7%), decabromodiphenyl ethane (DBDPE), and bis(2-ethylhexyl)tetrabromophthalate (BEH-TEBP) (both n = 5, 2.7%). Overall, 120 samples contained at least one HFR at a concentration exceeding 1000 mg/kg. In addition to the waste management implications of our findings, our data raise concerns about child exposure to HFRs during the use phase of these everyday items.-
Descrição: dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)-
Descrição: dc.descriptionSchool of Geography Earth and Environmental Sciences University of Birmingham, West Midlands-
Descrição: dc.descriptionQueensland Alliance for Environmental Health Sciences (QAEHS) The University of Queensland, 20 Cornwall Street-
Descrição: dc.descriptionSchool of Natural Sciences & Ryan Institute National University of Ireland-
Descrição: dc.descriptionInstitute of Science and Technology São Paulo State University (UNESP), Av. Três de Março, 511, Sorocaba- SP-
Descrição: dc.descriptionInstitute of Science and Technology São Paulo State University (UNESP), Av. Três de Março, 511, Sorocaba- SP-
Descrição: dc.descriptionFAPESP: 2019/06800–5-
Descrição: dc.descriptionFAPESP: 2022/00985–6-
Idioma: dc.languageen-
Relação: dc.relationEnvironmental Pollution-
???dc.source???: dc.sourceScopus-
Palavras-chave: dc.subjectBrominated flame retardants-
Palavras-chave: dc.subjectChild car seats-
Palavras-chave: dc.subjectChlorinated organophosphate esters-
Palavras-chave: dc.subjectCot mattresses-
Palavras-chave: dc.subjectWaste management-
Título: dc.titleElevated concentrations of halogenated flame retardants in waste childcare articles from Ireland-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional - Unesp

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