Greenness of procedures using NADES in the preparation of vegetal samples: Comparison of five green metrics

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MetadadosDescriçãoIdioma
Autor(es): dc.contributorUniversidade Estadual Paulista (UNESP)-
Autor(es): dc.contributorUniversidade Federal de Minas Gerais (UFMG)-
Autor(es): dc.contributorUniversidade de São Paulo (USP)-
Autor(es): dc.contributorUniversidade Federal do Paraná (UFPR)-
Autor(es): dc.creatorFerreira, Sabrina S.-
Autor(es): dc.creatorBrito, Thomas A.-
Autor(es): dc.creatorSantana, Ana P.R.-
Autor(es): dc.creatorGuimarães, Taciana G.S.-
Autor(es): dc.creatorLamarca, Rafaela S.-
Autor(es): dc.creatorFerreira, Karen C.-
Autor(es): dc.creatorGomes, Paulo C. F. Lima-
Autor(es): dc.creatorOliveira, Andrea-
Autor(es): dc.creatorAmaral, Clarice D.B.-
Autor(es): dc.creatorGonzalez, Mario H.-
Data de aceite: dc.date.accessioned2025-08-21T20:47:40Z-
Data de disponibilização: dc.date.available2025-08-21T20:47:40Z-
Data de envio: dc.date.issued2023-03-01-
Data de envio: dc.date.issued2023-03-01-
Data de envio: dc.date.issued2022-11-30-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.1016/j.talo.2022.100131-
Fonte completa do material: dc.identifierhttp://hdl.handle.net/11449/241405-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/241405-
Descrição: dc.descriptionThe principles of green analytical chemistry have led to the development of analytical procedures that are increasingly sustainable. Different metrics have been created for the evaluation of greenness, although determination of the green nature of new analytical methods remains challenging, including for extraction methods that involve the use of natural deep eutectic solvents (NADES). In this study, the following five chemical metrics for the evaluation of greenness were considered: National Environmental Methods Index (NEMI), Green Analytical Procedure Index (GAPI), Analytical Eco-Scale, Analytical GREEnness (AGREE), and White Analytical Chemistry (WAC). These methods were applied in evaluation of the environmental and sustainability characteristics of three different methods for the preparation of plant material samples: microwave-assisted extraction (MAE), ultrasound-assisted extraction (UAE), and microwave-assisted acid digestion (MW-AD). These methods employed different NADES as extraction solvents, as well as dilute nitric acid as an oxidizing agent, for the determination of As, Cd, Pb, and V by inductively coupled plasma mass spectrometry (ICP-MS). The NEMI metric found no differences between the MAE-NADES and UAE-NADES methods. The GAPI metric found differences between the MAE-NADES and UAE-NADES methods and identify the disadvantageous aspects of each step of the methods. The Analytical Eco-Scale and AGREE identified the MAE-NADES method as the greenest, while WAC-12 RGB indicated the UAE-NADES method as the greenest procedure. A detailed discussion is provided of the application of each metric, together with their differences and advantages.-
Descrição: dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)-
Descrição: dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)-
Descrição: dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)-
Descrição: dc.descriptionDepartment of Chemistry and Environmental Science National Institute for Alternative Technologies of Detection Toxicological Evaluation and Removal of Micropollutants and Radioactives (INCT-DATREM) São Paulo State University (UNESP), São José do Rio Preto-
Descrição: dc.descriptionDepartment of Chemistry Federal University of Minas Gerais, Belo Horizonte-
Descrição: dc.descriptionDepartment of Chemistry Federal University of São Paulo (UNIFESP), Diadema-
Descrição: dc.descriptionDepartment of Analytical Chemistry Physical Chemistry and Inorganic Chemistry National Institute for Alternative Technologies of Detection Toxicological Evaluation and Removal of Micropollutants and Radioactives (INCT-DATREM) Institute of Chemistry São Paulo State University (UNESP), Araraquara-
Descrição: dc.descriptionDepartment of Chemistry Federal University of Paraná (UFPR), Curitiba-
Descrição: dc.descriptionDepartment of Chemistry and Environmental Science National Institute for Alternative Technologies of Detection Toxicological Evaluation and Removal of Micropollutants and Radioactives (INCT-DATREM) São Paulo State University (UNESP), São José do Rio Preto-
Descrição: dc.descriptionDepartment of Analytical Chemistry Physical Chemistry and Inorganic Chemistry National Institute for Alternative Technologies of Detection Toxicological Evaluation and Removal of Micropollutants and Radioactives (INCT-DATREM) Institute of Chemistry São Paulo State University (UNESP), Araraquara-
Descrição: dc.descriptionFAPESP: #2014/50945-4-
Descrição: dc.descriptionFAPESP: #2015/08873-9-
Descrição: dc.descriptionFAPESP: #2017/18531-3-
Descrição: dc.descriptionFAPESP: #2019/22113-8-
Descrição: dc.descriptionFAPESP: #2021/14581-1-
Descrição: dc.descriptionCNPq: #465571/2014-0-
Descrição: dc.descriptionCAPES: #88887-
Descrição: dc.descriptionCAPES: #88887136426/2017/00-
Descrição: dc.descriptionCAPES: 485183/2020-00-
Formato: dc.formatapplication/pdf-
Idioma: dc.languageen-
Relação: dc.relationTalanta Open-
???dc.source???: dc.sourceScopus-
Palavras-chave: dc.subjectAnalytical Eco-scale-
Palavras-chave: dc.subjectAnalytical GREEnness (AGREE)-
Palavras-chave: dc.subjectGreen analytical procedure index (GAPI)-
Palavras-chave: dc.subjectNational environmental methods index (NEMI)-
Palavras-chave: dc.subjectNatural deep eutectic solvent (NADES)-
Palavras-chave: dc.subjectWhite analytical chemistry (WAC)-
Título: dc.titleGreenness of procedures using NADES in the preparation of vegetal samples: Comparison of five green metrics-
Tipo de arquivo: dc.typelivro digital-
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