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Metadados | Descrição | Idioma |
---|---|---|
Autor(es): dc.contributor | Universidade Estadual Paulista (UNESP) | - |
Autor(es): dc.contributor | Universidade Federal de São Carlos (UFSCar) | - |
Autor(es): dc.creator | Dakuzaku, Carolina S. [UNESP] | - |
Autor(es): dc.creator | Freschi, Gian P. G. [UNESP] | - |
Autor(es): dc.creator | De Moraes, Mercedes [UNESP] | - |
Autor(es): dc.creator | Nóbrega, Joaquim A. | - |
Autor(es): dc.creator | Gomes Neto, José A. [UNESP] | - |
Data de aceite: dc.date.accessioned | 2022-08-04T22:01:09Z | - |
Data de disponibilização: dc.date.available | 2022-08-04T22:01:09Z | - |
Data de envio: dc.date.issued | 2022-04-28 | - |
Data de envio: dc.date.issued | 2022-04-28 | - |
Data de envio: dc.date.issued | 2001-03-01 | - |
Fonte completa do material: dc.identifier | http://hdl.handle.net/11449/219247 | - |
Fonte: dc.identifier.uri | http://educapes.capes.gov.br/handle/11449/219247 | - |
Descrição: dc.description | A method has been developed for the direct determination of As in sugar by graphite furnace atomic absorption spectrometry with a transversely heated graphite atomizer (end-capped THGA) and longitudinal Zeeman-effect background correction. The thermal behavior of As during the pyrolysis and atomization steps was investigated in sugar solutions containing 0.2% (v/v) HNO3 using Pd, Ni, and a mixture of Pd + Mg as the chemical modifiers. For a 60-μL sugar solution, an aliquot of 8% (m/v) in 0.2% (v/v)HNO3 was dispensed into a pre-heated graphite tube at 70°C. Linear analytical curves were obtained in the 0.25 - 1.50-μg L-1 As range. Using 5 μg Pd and a first pyrolysis step at 600°C assisted by air during 40 s, the formation of a large amount of carbonaceous residue inside the atomizer was avoided. The characteristic mass was calculated as 24 pg As and the lifetime of the graphite tube was around 280 firings. The limit of detection (L.O.D.) based on integrated absorbance was 0.08 μg L-1 (4.8 pg As) and the typical relative standard deviation (n = 12) was 7% for a sugar solution containing 0.5 μg L-1. Recoveries of As added to sugar samples varied from 86 to 98%. The accuracy was checked in the direct analysis of eight sugar samples. A paired t-test showed that the results were in agreement at the 95% confidence level with those obtained for acid-digested sugar samples by GFAAS. | - |
Descrição: dc.description | Instituto de Química Universidade Estadual Paulista, PO Box 355, 14801-970 Araraquara-SP | - |
Descrição: dc.description | Departamento de Química Univ. Federal de São Carlos, São Carlos-SP | - |
Descrição: dc.description | Instituto de Química Universidade Estadual Paulista, PO Box 355, 14801-970 Araraquara-SP | - |
Formato: dc.format | 271-275 | - |
Idioma: dc.language | en | - |
Relação: dc.relation | Atomic Spectroscopy | - |
???dc.source???: dc.source | Scopus | - |
Título: dc.title | Direct determination of arsenic in sugar by GFAAS with transversely heated graphite atomizer and longitudinal Zeeman-effect background correction | - |
Tipo de arquivo: dc.type | livro digital | - |
Aparece nas coleções: | Repositório Institucional - Unesp |
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