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Metadados | Descrição | Idioma |
---|---|---|
Autor(es): dc.contributor | National University of Engineering | - |
Autor(es): dc.contributor | Universidade Estadual Paulista (Unesp) | - |
Autor(es): dc.contributor | Toxicological Evaluation and Removal of Micropollutants and Radioactives (INCT-DATREM) | - |
Autor(es): dc.creator | Ruiz-Córdova, Gerson A. [UNESP] | - |
Autor(es): dc.creator | Villa, Javier E.L. [UNESP] | - |
Autor(es): dc.creator | Khan, Sabir [UNESP] | - |
Autor(es): dc.creator | Picasso, Gino | - |
Autor(es): dc.creator | Del Pilar Taboada Sotomayor, Maria [UNESP] | - |
Data de aceite: dc.date.accessioned | 2022-02-22T00:50:33Z | - |
Data de disponibilização: dc.date.available | 2022-02-22T00:50:33Z | - |
Data de envio: dc.date.issued | 2021-06-25 | - |
Data de envio: dc.date.issued | 2021-06-25 | - |
Data de envio: dc.date.issued | 2021-05-15 | - |
Fonte completa do material: dc.identifier | http://dx.doi.org/10.1016/j.aca.2021.338443 | - |
Fonte completa do material: dc.identifier | http://hdl.handle.net/11449/207540 | - |
Fonte: dc.identifier.uri | http://educapes.capes.gov.br/handle/11449/207540 | - |
Descrição: dc.description | The present work shows the synergistic application of reflectance spectroscopy and core-shell molecularly imprinted polymer (MIP) for rapid quantification of tartrazine in soft drinks. Studies evaluated the performance of the MIPs synthesized in the presence of silica nanoparticles unfunctionalized and functionalized with [3-(methacryloyloxy)propyl]trimethoxysilane. Although the use of functionalized silica nanoparticles promoted the highest adsorption capability of tartrazine, the material was found to be less selective when it was applied in real samples. Interestingly, the most accurate results were obtained via the application of the MIP synthesized in the presence of unfunctionalized silica nanoparticles (SiO2@MIP). The optimized core-shell MIP was also characterized by Raman spectroscopy and scanning electron microscopy. The use of direct reflectance spectroscopy in the analyte detection strategy after the template extraction from the MIPs resulted in faster and more accurate results than conventional UV–Visible spectroscopy. With regard to the analysis of the soft drink samples, no significant differences were found between the results obtained from the proposed reflectance spectroscopy-based technique and those obtained from the comparative high-performance liquid chromatography technique. Under optimized conditions, this method displayed a linear range of 1.0–12.5 μmol L−1 with LOD and LOQ values of 0.303 and 1.0 μmol L−1, respectively. The selectivity factor (β) ranged between 1.4 up to 264 showed better recognition of tartrazine in front of other dyes. Based on the results obtained, the proposed method is found to be suitable for rapid determination of tartrazine in food samples with complex matrices without the need of applying tedious sample preparation and cost-demanding instruments. | - |
Descrição: dc.description | Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) | - |
Descrição: dc.description | Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) | - |
Descrição: dc.description | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) | - |
Descrição: dc.description | Fondo Nacional de Desarrollo Científico, Tecnológico y de Innovación Tecnológica | - |
Descrição: dc.description | Laboratory of Physical Chemistry Research Faculty of Sciences National University of Engineering, Av. Tupac Amaru 210 Rimac | - |
Descrição: dc.description | Department of Analytical Chemistry Institute of Chemistry São Paulo State University (UNESP) | - |
Descrição: dc.description | National Institute of Alternative Technologies for Detection Toxicological Evaluation and Removal of Micropollutants and Radioactives (INCT-DATREM) | - |
Descrição: dc.description | Department of Analytical Chemistry Institute of Chemistry São Paulo State University (UNESP) | - |
Idioma: dc.language | en | - |
Relação: dc.relation | Analytica Chimica Acta | - |
???dc.source???: dc.source | Scopus | - |
Palavras-chave: dc.subject | Acid yellow 23 | - |
Palavras-chave: dc.subject | Diffuse reflectance | - |
Palavras-chave: dc.subject | HPLC | - |
Palavras-chave: dc.subject | MIP | - |
Palavras-chave: dc.subject | Precipitation method | - |
Palavras-chave: dc.subject | Silica nanoparticles | - |
Título: dc.title | Surface molecularly imprinted core-shell nanoparticles and reflectance spectroscopy for direct determination of tartrazine in soft drinks | - |
Tipo de arquivo: dc.type | livro digital | - |
Aparece nas coleções: | Repositório Institucional - Unesp |
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