In Situ Generation of Fullerene from a Poly(fullerene)

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MetadadosDescriçãoIdioma
Autor(es): dc.contributorInstitut des Science Analytiques et Physico-Chimie pour l'Environnement et les Materiaux-
Autor(es): dc.contributorEberhard Karls Universität Tübingen-
Autor(es): dc.contributorUniversidade Estadual Paulista (Unesp)-
Autor(es): dc.contributorBELECTRIC OPV GmbH (now OPVIUS GmbH)-
Autor(es): dc.contributorSolar Factory of the Future-
Autor(es): dc.creatorSilva, Hugo Santos-
Autor(es): dc.creatorRamanitra, Hasina H.-
Autor(es): dc.creatorBregadiolli, Bruna A. [UNESP]-
Autor(es): dc.creatorTournebize, Aurélien-
Autor(es): dc.creatorBégué, Didier-
Autor(es): dc.creatorDowland, Simon A.-
Autor(es): dc.creatorLartigau-Dagron, Christine-
Autor(es): dc.creatorGraeff, Carlos F. O. [UNESP]-
Autor(es): dc.creatorDistler, Andreas-
Autor(es): dc.creatorPeisert, Heiko-
Autor(es): dc.creatorChassé, Thomas-
Autor(es): dc.creatorHiorns, Roger C.-
Data de aceite: dc.date.accessioned2022-02-22T00:33:08Z-
Data de disponibilização: dc.date.available2022-02-22T00:33:08Z-
Data de envio: dc.date.issued2020-12-11-
Data de envio: dc.date.issued2020-12-11-
Data de envio: dc.date.issued2019-10-31-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.1002/polb.24888-
Fonte completa do material: dc.identifierhttp://hdl.handle.net/11449/201285-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/201285-
Descrição: dc.descriptionThis article appraises the thermal, photo- and photo-oxidative stability of poly(fullerene)-alt-[bismethylbenzene)]s (PFBMBs) prepared by the atom transfer radical addition polymerization (ATRAP) with particular attention paid to their use as additives in organic photovoltaic devices. PFBMBs are of interest due to their well-defined structures based on alternating, main-chain, fullerene-methylene links. This work shows by way of a wide range of characterization techniques and a small library of PFBMBs with varying side chains, however, that PFBMBs are relatively unstable. Given that prior work has shown that other main-chain fullerene polymers, such as poly(pyrrolidinofullerene)s, are inherently stable, we suggest a degradation mechanism specific to the fullerene-methylene links of PFBMBs, which explains their unusual behavior. This work suggests that polymers based on fullerene each have their own specific stabilities and qualities and that PFBMBs might be of more use in purposes other than OPVs where in situ delivery of fullerene is required, for example, in medical applications. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019, 57, 1434–1452.-
Descrição: dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)-
Descrição: dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)-
Descrição: dc.descriptionCNRS/Univ Pau & Pays Adour Institut des Science Analytiques et Physico-Chimie pour l'Environnement et les Materiaux-
Descrição: dc.descriptionInstitute for Physical and Theoretical Chemistry Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18-
Descrição: dc.descriptionDepartamento de Física – FC – UNESP, Av. Luiz Edmundo Carrijo Coube, 14-01-
Descrição: dc.descriptionBELECTRIC OPV GmbH (now OPVIUS GmbH), Landgrabenstraße 94-
Descrição: dc.descriptionBavarian Center for Applied Energy Research Solar Factory of the Future, Fürther Str. 250-
Descrição: dc.descriptionDepartamento de Física – FC – UNESP, Av. Luiz Edmundo Carrijo Coube, 14-01-
Descrição: dc.descriptionFAPESP: 2011/02205-3-
Descrição: dc.descriptionCAPES: BEX 11216-12-3-
Formato: dc.format1434-1452-
Idioma: dc.languageen-
Relação: dc.relationJournal of Polymer Science, Part B: Polymer Physics-
???dc.source???: dc.sourceScopus-
Palavras-chave: dc.subjectatom transfer radical addition-
Palavras-chave: dc.subjectdegradation-
Palavras-chave: dc.subjectFullerenes-
Palavras-chave: dc.subjectorganic photovoltaic-
Palavras-chave: dc.subjectorganic solar cell-
Palavras-chave: dc.subjectphotoreactive effects-
Palavras-chave: dc.subjectpoly(fullerene)-
Título: dc.titleIn Situ Generation of Fullerene from a Poly(fullerene)-
Tipo de arquivo: dc.typelivro digital-
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