Enhancement of sulfonated poly(ether ether ketone)-based proton exchange membranes doped with different ionic liquids cations

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Autor(es): dc.contributorUniversidade Federal de São Carlos (UFSCar)-
Autor(es): dc.contributorUniversidade Estadual Paulista (Unesp)-
Autor(es): dc.contributorUniversidade Federal do Rio Grande do Sul-
Autor(es): dc.creatorda Trindade, Letícia Guerreiro [UNESP]-
Autor(es): dc.creatorZanchet, Letícia-
Autor(es): dc.creatorSouza, Josiane Carneiro-
Autor(es): dc.creatorLeite, Edson Roberto-
Autor(es): dc.creatorMartini, Emilse Maria Agostini-
Autor(es): dc.creatorPereira, Ernesto Chaves-
Data de aceite: dc.date.accessioned2022-02-22T00:26:25Z-
Data de disponibilização: dc.date.available2022-02-22T00:26:25Z-
Data de envio: dc.date.issued2020-12-11-
Data de envio: dc.date.issued2020-12-11-
Data de envio: dc.date.issued2019-12-31-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.1007/s11581-020-03684-5-
Fonte completa do material: dc.identifierhttp://hdl.handle.net/11449/199088-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/199088-
Descrição: dc.descriptionHerein, to balance the overall performance of SPEEK membrane, the imidazolium hydrogen sulfate (Im.HSO4), 1-methylimidazolium hydrogen sulfate (MI.HSO4), and 1-butyl-3-methylimidazolium hydrogen sulfate (BMI.HSO4) ionic liquids (ILs) were used as dopants in polymer matrix. A series of SPEEK/ionic liquid composite membranes were successfully fabricated by casting method and evaluated. Comparative studies showed that the membranes doped with 5 wt.% of MI.HSO4 or BMI.HSO4 ILs showed an increase in the proton conductivity of 50% and 30% at 80 °C, respectively, compared with the pristine SPEEK membrane. The proton exchange membrane fuel cell (PEMFC) performance demonstrated that the membrane doped with 5 wt.% of BMI.HSO4 IL (SBMI5) has the highest current density value and the highest power density without loss of performance as temperature increases. This result indicates that this membrane is promising for fuel cells application.-
Descrição: dc.descriptionChemistry Department Federal University of São Carlos, P. O. Box 676-
Descrição: dc.descriptionDepartment of Chemistry Universidade Estadual Paulista–Unesp, P.O. Box 473-
Descrição: dc.descriptionLRC-Institute of Chemistry Universidade Federal do Rio Grande do Sul, P. O. Box 15003-
Descrição: dc.descriptionDepartment of Chemistry Universidade Estadual Paulista–Unesp, P.O. Box 473-
Idioma: dc.languageen-
Relação: dc.relationIonics-
???dc.source???: dc.sourceScopus-
Palavras-chave: dc.subjectFuel cell-
Palavras-chave: dc.subjectIonic liquid-
Palavras-chave: dc.subjectProton exchange membranes-
Palavras-chave: dc.subjectSulfonated poly(ether ether ketone)-
Título: dc.titleEnhancement of sulfonated poly(ether ether ketone)-based proton exchange membranes doped with different ionic liquids cations-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional - Unesp

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