Luminescent spherical particles of lanthanide-based infinite coordination polymers with tailorable sizes

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.contributorUniversidade Estadual Paulista (Unesp)-
Autor(es): dc.creatorArroyos, Guilherme [UNESP]-
Autor(es): dc.creatorFrem, Regina C. G. [UNESP]-
Data de aceite: dc.date.accessioned2022-02-22T00:25:20Z-
Data de disponibilização: dc.date.available2022-02-22T00:25:20Z-
Data de envio: dc.date.issued2020-12-11-
Data de envio: dc.date.issued2020-12-11-
Data de envio: dc.date.issued2020-04-14-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.1039/d0ce00155d-
Fonte completa do material: dc.identifierhttp://hdl.handle.net/11449/198723-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/198723-
Descrição: dc.descriptionInfinite coordination polymers (ICPs) are compounds usually obtained as spherical particles exhibiting amorphous phases in powder X-ray diffraction patterns. In the present work, we report an ICP system based on rare-earth ions with pyrazole-3,5-dicarboxylate as a linker and malonate as a coordination modulator. The compounds exhibit a 2D MOF structure. Three different synthetic routes were used, namely microwave-assisted, solvothermal and gel diffusion. The syntheses yield single-phase spherical particles, which were characterized by PXRD, 1H NMR, CHN, FTIR, TGA, SEM and TEM. Photoluminescence spectroscopy was carried out to study the luminescence properties of the Eu3+ and Tb3+-based samples. With the different-sized particles obtained, we could elucidate the intricate microstructure of the spheres and propose a reason behind the observed amorphous phases in the PXRD patterns.-
Descrição: dc.descriptionInstitute of Chemistry São Paulo State University UNESP-
Descrição: dc.descriptionInstitute of Chemistry São Paulo State University UNESP-
Formato: dc.format2439-2446-
Idioma: dc.languageen-
Relação: dc.relationCrystEngComm-
???dc.source???: dc.sourceScopus-
Título: dc.titleLuminescent spherical particles of lanthanide-based infinite coordination polymers with tailorable sizes-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional - Unesp

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