Thermal behaviour of binuclear cyclopalladated compounds containing anionic azo-ligands

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.contributorUniversidade Estadual Paulista (Unesp)-
Autor(es): dc.contributorUniv Catolica Brasilia-
Autor(es): dc.creatorAlmeida, E. T. de-
Autor(es): dc.creatorMauro, A. E.-
Autor(es): dc.creatorSantana, A. M.-
Data de aceite: dc.date.accessioned2022-02-22T00:06:43Z-
Data de disponibilização: dc.date.available2022-02-22T00:06:43Z-
Data de envio: dc.date.issued2020-12-09-
Data de envio: dc.date.issued2020-12-09-
Data de envio: dc.date.issued2002-01-01-
Fonte completa do material: dc.identifierhttp://hdl.handle.net/11449/195728-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/195728-
Descrição: dc.descriptionThis paper deals with the thermal behavior study of cyclopalladated complexes obtained from reactions of [Pd(dmba)N-3](2) (1), dmba = N,N-dimethylbenzylamine, with azole-compunds, such as, the anionic ligands pyrazolate (pz), imidazolate (imz) and 3,5-dimethyl-pyrazolate (3,5-dmpz), The characterization of the binuclear complexes [Pd(dmba)(mu-pz)](2) (2), [Pd(dmba)(mu-imz)](2) (3) and [Pd(dmba)(mu-3.5-dmpz)](2) (4) was carried out by elemental analysis, IR and NMR spectroscopy, Their thermal behaviour has been investigated and the final product was identified by X-ray powder diffractometry which showed the formation of Pd(0) as final decomposition product.-
Descrição: dc.descriptionUNESP, Inst Quim, Dept Quim Geral & Inorgan, BR-14801970 Araraquara, SP, Brazil-
Descrição: dc.descriptionUniv Catolica Brasilia, Curso Quim, BR-72030170 Brasilia, DF, Brazil-
Descrição: dc.descriptionUNESP, Inst Quim, Dept Quim Geral & Inorgan, BR-14801970 Araraquara, SP, Brazil-
Formato: dc.format201-210-
Idioma: dc.languagees-
Publicador: dc.publisherEditora Unesp-
Relação: dc.relationEcletica Quimica-
???dc.source???: dc.sourceWeb of Science-
Palavras-chave: dc.subjectcyclopalladated-
Palavras-chave: dc.subjectthermal analysis-
Palavras-chave: dc.subjectpyrazolate-
Palavras-chave: dc.subjectimidazolate-
Palavras-chave: dc.subject3,5-dimethyl-pyrazolate-
Título: dc.titleThermal behaviour of binuclear cyclopalladated compounds containing anionic azo-ligands-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional - Unesp

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