The cathodic cleavage of the nitrobenzoyl group from protected aliphatic amines in N,N-dimethylformamide

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.contributorUniversidade Estadual Paulista (Unesp)-
Autor(es): dc.contributorUniversidade de São Paulo (USP)-
Autor(es): dc.creatorJorge, SMA-
Autor(es): dc.creatorCampos, P. M. de-
Autor(es): dc.creatorStradiotto, N. R.-
Data de aceite: dc.date.accessioned2022-02-22T00:06:37Z-
Data de disponibilização: dc.date.available2022-02-22T00:06:37Z-
Data de envio: dc.date.issued2020-12-09-
Data de envio: dc.date.issued2020-12-09-
Data de envio: dc.date.issued1999-05-01-
Fonte completa do material: dc.identifierhttp://hdl.handle.net/11449/195687-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/195687-
Descrição: dc.descriptionThe electrochemical reduction of aliphatic amines protected by the 4- and 3-nitrobenzoyl group in N,N-dimethylformamide was reported. The compounds are reduced in two cathodic steps. The first one at about -1 V vs. SCE occurs with the formation of the rather stable anion radicals, involving one electron transfer. The reduction to dianion occurs at potentials between -1.5 and -2.0 V vs. SCE by an ECE process and leads to cleavage of the CN bond in yields above 50%.-
Descrição: dc.descriptionUNESP, Inst Biociencias, Dept Quim, BR-18618000 Botucatu, SP, Brazil-
Descrição: dc.descriptionUSP, Fac Filosofia Ciencias & Letras Ribeirao Pret, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil-
Descrição: dc.descriptionUNESP, Inst Biociencias, Dept Quim, BR-18618000 Botucatu, SP, Brazil-
Formato: dc.format176-180-
Idioma: dc.languageen-
Publicador: dc.publisherSoc Brasileira Quimica-
Relação: dc.relationJournal Of The Brazilian Chemical Society-
???dc.source???: dc.sourceWeb of Science-
Palavras-chave: dc.subjectnitrobenzoyl group-
Palavras-chave: dc.subjectcathodic cleavage-
Palavras-chave: dc.subjectaliphatic amines-
Título: dc.titleThe cathodic cleavage of the nitrobenzoyl group from protected aliphatic amines in N,N-dimethylformamide-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional - Unesp

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