Phase formation maps in Zr48Cu46.5Al4Nb1.5 bulk metallic glass composites as a function of cooling rate and oxygen concentration

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MetadadosDescriçãoIdioma
Autor(es): dc.contributorUniversidade de São Paulo (USP)-
Autor(es): dc.contributorColorado Sch Mines-
Autor(es): dc.contributorUniversidade Estadual Paulista (Unesp)-
Autor(es): dc.creatorCampos Neto, Nelson Delfino de-
Autor(es): dc.creatorPereira, Flavio Soares-
Autor(es): dc.creatorAntonio, Selma Gutierrez [UNESP]-
Autor(es): dc.creatorGuo, Yaofeng-
Autor(es): dc.creatorClarke, Amy J.-
Autor(es): dc.creatorKaufrnan, Michael J.-
Autor(es): dc.creatorOliveira, Marcelo Falcao de-
Data de aceite: dc.date.accessioned2022-02-22T00:04:40Z-
Data de disponibilização: dc.date.available2022-02-22T00:04:40Z-
Data de envio: dc.date.issued2020-12-09-
Data de envio: dc.date.issued2020-12-09-
Data de envio: dc.date.issued2019-11-30-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.1016/j.matchar.2019.109932-
Fonte completa do material: dc.identifierhttp://hdl.handle.net/11449/195057-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/195057-
Descrição: dc.descriptionA design of experiments (DoE) approach was employed to systematically characterize the effects of both oxygen concentration and cooling rate on the amorphous and crystalline phase fractions in the Zr48Cu46.5Al4Nb1.5 bulk metallic glass composite (BMGC) alloy. Specifically, four distinct oxygen concentrations and five distinct cooling rates were used. Phase quantification was achieved using Rietveld refinement of synchrotron X-ray diffraction (XRD) data. Electron probe microanalysis (EPMA) using wavelength dispersive spectroscopy (WDS) revealed that the big-cube crystalline phase may scavenge oxygen from the amorphous matrix of a 2864 +/- 47 wppm oxygen sample. Transmission electron microscopy (TEM) of the alloy containing 340 +/- 25 wppm oxygen revealed the presence of an amorphous matrix with partially-transformed colonies of B2 (Pm-3m) where the transformation product was a B19' superstructure (Cm space group) instead of the more common B19' superstructure (P2(1)/m space group); this was in agreement with the Rietveld refinement results. An orientation relationship between the B2 and B19' phases was observed as expected. Finally, it was possible to produce thicker sections (5 mm vs. 3.5 mm) with the desired composite structure ( similar to 80% amorphous fraction with similar to 20% B2/ B19') compared with previous BMGC studies on similar compositions.-
Descrição: dc.descriptionBoeing Research & Technology Brazil (BRT-Brazil)-
Descrição: dc.descriptionCenter for Advanced Non-Ferrous Structural Alloys (CANFSA), a National Science Foundation Industry/University Cooperative Research Center (I/UCRC) at the Colorado School of Mines-
Descrição: dc.descriptionUniv Sao Paulo, Dept Mat Engn, Sao Carlos Sch Engn, Joao Dagnone Ave 1100, BR-13563120 Sao Carlos, SP, Brazil-
Descrição: dc.descriptionColorado Sch Mines, George S Ansell Dept Met & Mat Engn, 1500 Illinois St, Golden, CO 80401 USA-
Descrição: dc.descriptionPaulista State Univ Julio de Mesquita Filho, Chem Inst Araraquara, Francisco Degni St 55, BR-14800900 Araraquara, SP, Brazil-
Descrição: dc.descriptionPaulista State Univ Julio de Mesquita Filho, Chem Inst Araraquara, Francisco Degni St 55, BR-14800900 Araraquara, SP, Brazil-
Descrição: dc.descriptionCenter for Advanced Non-Ferrous Structural Alloys (CANFSA), a National Science Foundation Industry/University Cooperative Research Center (I/UCRC) at the Colorado School of Mines: 1624836-
Formato: dc.format7-
Idioma: dc.languageen-
Publicador: dc.publisherElsevier B.V.-
Relação: dc.relationMaterials Characterization-
???dc.source???: dc.sourceWeb of Science-
Palavras-chave: dc.subjectBulk metallic glass composites-
Palavras-chave: dc.subjectOxygen-
Palavras-chave: dc.subjectCooling rate-
Palavras-chave: dc.subjectsynchrotron XRD-
Palavras-chave: dc.subjectRietveld refinement-
Palavras-chave: dc.subjectTEM-
Título: dc.titlePhase formation maps in Zr48Cu46.5Al4Nb1.5 bulk metallic glass composites as a function of cooling rate and oxygen concentration-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional - Unesp

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