On the effects of hydroxyl substitution degree and molecular weight on mechanical and water barrier properties of hydroxypropyl methylcellulose films

Registro completo de metadados
MetadadosDescriçãoIdioma
Autor(es): dc.contributorUniversidade Estadual Paulista (UNESP)-
Autor(es): dc.creatorOtoni, Caio G.-
Autor(es): dc.creatorLorevice, Marcos V.-
Autor(es): dc.creatorMoura, Marcia R. de-
Autor(es): dc.creatorMattoso, Luiz H. C.-
Data de aceite: dc.date.accessioned2021-03-10T23:57:01Z-
Data de disponibilização: dc.date.available2021-03-10T23:57:01Z-
Data de envio: dc.date.issued2018-11-26-
Data de envio: dc.date.issued2018-11-26-
Data de envio: dc.date.issued2018-04-01-
Fonte completa do material: dc.identifierhttp://dx.doi.org/10.1016/j.carbpol.2018.01.016-
Fonte completa do material: dc.identifierhttp://hdl.handle.net/11449/163814-
Fonte: dc.identifier.urihttp://educapes.capes.gov.br/handle/11449/163814-
Descrição: dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)-
Descrição: dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)-
Descrição: dc.descriptionProcesso FAPESP: 2013/14366-7-
Descrição: dc.descriptionProcesso FAPESP: 2014/23098-9-
Descrição: dc.descriptionCNPq: 402287/2013-4-
Descrição: dc.descriptionIn line with the increasing demand for sustainable packaging materials, this contribution aimed to investigate the film-forming properties of hydroxypropyl methylcellulose (HPMC) to correlate its chemical structure with film properties. The roles played by substitution degree (SD) and molecular weight (M-w) on the mechanical and water barrier properties of HPMC films were elucidated. Rheological, thermal, and structural experiments supported such correlations. SD was shown to markedly affect film affinity and barrier to moisture, glass transition, resistance, and extensibility, as hydroxyl substitution lessens the occurrence of polar groups. M-w affected mostly the rheological and mechanical properties of HPMC-based materials. Methocel (R) E4 M led to films featuring the greatest tensile strength (ca., 67 MPa), stiffness (ca., 1.8 GPa), and extensibility (ca., 17%) and the lowest permeability to water vapor (ca., 0.9 g mm kPa(-1) h(-1) m(-2)). These properties, which arise from its longer and less polar chains, are desirable for food packaging materials.-
Formato: dc.format105-111-
Idioma: dc.languageen-
Publicador: dc.publisherElsevier B.V.-
Relação: dc.relationCarbohydrate Polymers-
Relação: dc.relation1,428-
Direitos: dc.rightsopenAccess-
Palavras-chave: dc.subjectBiopolymer-
Palavras-chave: dc.subjectCellulose derivative-
Palavras-chave: dc.subjectCellulose ether-
Palavras-chave: dc.subjectHypromellose-
Palavras-chave: dc.subjectFood packaging-
Palavras-chave: dc.subjectEdible film-
Título: dc.titleOn the effects of hydroxyl substitution degree and molecular weight on mechanical and water barrier properties of hydroxypropyl methylcellulose films-
Tipo de arquivo: dc.typelivro digital-
Aparece nas coleções:Repositório Institucional - Unesp

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